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Correspondence, manuscripts, notes, drafts of speeches, appointment books, subject files, documents, photographs, memorabilia and printed materials. There are notes from her lectures on Sociology at Adelphi College in 1911-1912; papers from 1912-1932, when Perkins served on the Commission for Safety and on the Industrial Commission of New York State; the main body of the material is from the period of her cabinet office, 1933-1945; and some items from her days on the Civil Service Commission, 1946-1953. Also included are personal and family papers.

Correspondence, manuscripts, memoranda, receipts, certificates, financial and legal documents, envelopes, clippings, pamphlets, and other printed materials dealing with social and family relationships, the sons' education, professions, and military careers, the Mexican-American War and the Civil War, real estate and financial matters, and with the deaths and bequests of various family members. Among the cataloged correspondents are: Alexander Hamilton, John Church Hamilton, Gen. Schuyler Hamilton, Ralph Isaacs Ingersoll, Charles Augustus Peabody, Gen. J. Fred Pierson, Gen. Winfield Scott, Martin Van Buren, and a manuscript by George Washington.