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The collection consists of correspondence, manuscripts and memoirs, documents, minutes of meetings, financial records, photographs, maps, and printed materials. Cataloged correspondents include Grand Duke Nikolaĭ Nikolaevich and General Petr Wrangel. Manuscripts include memoirs by Konstantin Rozen on his military service from 1902-1917, and a memoir by F. N. Bui︠a︡k entitled "Vospominanii︠a︡ starogo kavalergarda 1885-1902." Subject files are on Kadry Voĭsk Ofit︠s︡erov (Cadres of Military Officers) in Belgrade and Soi︠u︡z Russkikh Ofit︠s︡erov (Union of Russian Officers), emigre Russian military organizations. Documents concern Rozen's family and estate in Vitebsk province. Minutes of meetings concern the Kavalergardskai︠a︡ Semi︠́a︡ (Cavalry Guard Family). Financial records cover the fundraising activities of Soi︠u︡z Russkikh Ofit︠s︡erov and the estate. Photographs are of the estate, and maps are of the Vitebsk region and the estate grounds. Printed materials concern the estate and the above mentioned military organizations, and include copies of the news bulletin"Vestnik Kavalergardskoĭ Semí.".

Correspondence, manuscripts, documents, photographs, printed materials, and coins of Marii︠a︡ A. Svi︠a︡topolk-Mirskai︠a︡ and her son Nikolaĭ V. Svi︠a︡topolk Mirskiĭ. The correspondence is primarily from members of the Imperial family (such as Grand Duke Nikolaĭ Nikolaevich and dowager Empress Marii︠a︡ Fedorovna) to Marii︠a︡ Svi︠a︡topolk-Mirskai︠a︡. Most of it dates from the 1920's and 1930's and much of it is mounted in scrapbooks. The manuscripts include Basil Strandman's "Balkan Reminiscences." Among the documents are diplomas, certificates, passports and Imperial decrees dating back to 1832. The photographs include a photograph of Metropolitan Evlogiĭ and several dozen copies of Imperial family photographs. There are also many photographs of paintings, icons and architecture. The subject files consist of materials relating to the Notbek family, the Mariĭnskoe Sestrichestvo (to which Marii︠a︡ Svi︠a︡topolk-Mirskai︠a︡ belonged), and the Iverskai︠a︡ Church in Belgrade. Among the printed materials are 12 issues of "Khudozhestvennye Sokrovishcha Rossii" (1901)"Mʹemoires du regne de Catherine.."(Amsterdam, 1729), and "Thʹeâtre de l'Hermitage de Catherine II.."(Paris, 1799?).

Most of the collection concerns the Cossacks in the emigration in the 1920s. Correspondents include Petr Krasnov, Aleksandr Lukomskiĭ, Afrikan Bogaevskiĭ, and Grand Duke Nikolaĭ Nikolaevich. There are White intelligence reports from the Civil War in the south, and manuscripts, correspondence, and mimeographed bulletins relating to the Cossacks in Europe in the 1920s. Printed materials consist of anti-Semitic Russian publications, including issues of "Nat︠s︡ii︠a︡" and "Zhidoved" from the 1930s.

The photo album depicts the Visit of his Imperial Majesty to the Headquarters of the Commander-in Chief, dating from 21-23 September 1914. The album includes 70 photographs, both candids and posed shots. Tsar Nicholas II actually only appears in a few, as does Grand Duke Nikolaĭ Nikolaevich; more of the photographs are of scenes and soldiers, apparently around the army headquarters.

The collection contains RNK correspondence, documents, photographs, subject files, organizational records and printed materials. There are letters from Boris Bakhmeteff, Pavel and Petr Dolgorukov, Zinaida Gippius, Aleksandr Kutepov, Dmitrii Merezhovskii, Bernard Pares, Ariadna Tyrkova-Williams, George Vernadsky, and Petr Vrangel. There is a short essay by Aleksandra Tolstaia about her father. The manuscripts relate to political, historical and sociological issues. Most of the subject files relate to emigre organizations other than the RNK, while those of the RNK are classified into files of financial records, bulletins, minutes and lists of names and addresses. Among the printed materials are brochures and pamphlets, clippings, newspapers, and books.