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The papers consist of correspondence, manuscripts, documents, subject files, photographs, and printed materials. Correspondence in the collection includes 1 item from Ivan Bunin, 2 from Vladimir Davydov, and many from G. A. Alekseev. Mendeleev's extensive memoirs, "Svet i teni v moei zhizni," discuss his childhood and youth, government service, World War I, the 1917 Revolution and the Civil War, and life in the emigration up to 1933. Subject files in this collection concern the Prague Russian Archive, the Union of the Russian Nobility, the Russian Imperial family in the emigration, and other topics. Printed materials include an almost complete set of the weekly "Parizhskii Vestnik" (1942-1944).

Most of the collection concerns the Russian emigration in interwar Europe; a sizeable part deals with the Kadet (Constitutional Democrat) Party in the Russian Civil War. There is correspondence, manuscripts, subject files, photographs, and printed materials. There are many letters by liberal figures, such as Astrov, Viktor Chelishchev, Petr I︠U︡renev, Aleksandr Kizevetter, Pavel Mili︠u︡kov, Vladimir D. Nabokov, Vladimir Obolenskiĭ, Panina, and Ivan Petrunkevich. There are also letters from Ivan Bilibin, Alice Masaryk, and Thomas Masaryk. Manuscripts are chiefly by Astrov, and include memoirs, poems, and lectures. There are also memoirs by Panina, and eulogies by various people on Astrov. Subject files from 1917-1920 have materials on Panina's arrest and trial by the Bolsheviks, Kadet conferences, protocols of meetings of the Kadet Party central committee, and other items. Files on the emigration deal with the Russkiĭ Ochag (Russian Hearth) and other bodies, especially in Czechoslovakia. There are photographs of Astrov, Kizevetter, Nikodim Kondakov, Alice Masaryk, Panina, and others. Printed materials include books, clippings, and offprints by Astrov and others.