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The collection includes correspondence, manuscripts, memoirs, diaries, notes, subject files, documents, photographs, and printed materials. Most of the material in the collection concerns Nikolaev's tenure as military attachʹe at the Russian embassy in Washington. Cataloged correspondents include Mikhail T. Florinsky and Geroid T. Robinson. There is a typescript by Vasiliĭ O. Kli︠u︡chevskiĭ, "Kratkoe posobie po russkoĭ istorii." Among the correspondence are cablegrams and official communications to the Russian embassy during World War I and the revolutionary period. Manuscripts, mostly by Nikolaev, concern contemporary and historical military topics. Diaries and memoirs deal with Nikolaev's travels to Europe during World War I and his activities as military attachʹe. Among orders granted to Nikolaev is the "Order of the Sacred Treasure," signed and sealed by the Japanese Emperor Meiji (1911). Printed materials include many articles by Nikolaev.

These papers consist of correspondence, manuscripts, documents, and printed materials. Most of the correspondence concerns Florinsky's publications and editorial work. Among the correspondents are Boris Bakhmeteff, Michael Karpovich, Aleksandr Meyendorff, Bernard Pares, James T. Shotwell, and Dmitriĭ Svi︠a︡topolk-Mirskiĭ: there are one or two items each from John Dewey, Herbert Hoover, Edwin Seligman, and Harry S. Truman. Manuscripts by Florinsky include his "Russia: A Short History" and some minor articles and book reviews. Other manuscripts include a poem by Bernard Pares and a study by Sergeĭ Prokopovich of the Soviet five-year plan of 1946-50; there is also a photograph of Meyendorff. Documents concern Florinsky's career at Columbia and also include book contracts. Printed materials consist chiefly of reviews of his works and reviews he wrote of others' books.